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Biology subjects

Kalyon, D. M.

Publications and source records attributed to Kalyon, D. M..

2 recordsLinked to original sources

Microgradients in porosity and canal diameter in femur bone

Bone exhibits hierarchical structural gradients that optimize mechanical performance and regenerative potential. Longitudinal and radial variations in cortical porosity and canal architecture influence load distribution, vascularization, and remodeling. Understanding these gradients is essential for designing scaffolds and implants that mimic native bone structure and function. This study quantified longitudinal and radial microgradients in cortical porosity and canal diameter along the rabbit femur and explored their implications for bone regeneration and repair implant design. Rabbit femora were divided into proximal, mid-shaft, and distal regions. High-resolution micro-computed tomography quantified cortical thickness, porosity, and canal diameter along radial and longitudinal axes in micron-scale resolutions. Compressive mechanical testing of cortical slices determined local moduli, which were correlated with microstructural parameters to establish structure-function relationships. Cortical thickness peaked at the mid-shaft and decreased toward both ends. Porosity and canal diameter increased radially toward the medullary cavity and longitudinally toward the bone ends. Upto 500 micron cortical thickness from the outer surface toward modullary cavity, porosity and canal diameter ranged, respectively, from ~5% and 40 {micro}m at the mid-shaft to ~40% and 110 {micro}m at the ends. At 750 micron cortical thickness, porosity and canal diameter ranged, respectively, from ~5% and 50 {micro}m at the mid-shaft to ~80% and 200 {micro}m at the ends. As expected, compressive moduli declined linearly with increasing porosity and canal size. The mid-shaft, with the lowest porosity and smallest canals, exhibited the highest modulus of around 15{square}MPa, which decreased to 5{square}MPa toward the ends. The rabbit femur displays distinct longitudinal and radial microgradients in porosity and canal architecture that govern local stiffness. These gradients define structural benchmarks for designing functionally graded tissue engineering scaffolds and bone implants that replicate native tissue structure and stiffness transitions to promote osteoconduction, osteoinduction, osteogenesis in bone regeneration and improve osseointegration of bone implants.

bioengineering↗

Advanced Bioprinting of Hydrogels with Controlled Mineral Gradients for Regenerative Engineering of the Osteochondral Interface

The osteochondral (OC) interface exhibits a mineral gradient in the subchondral bone and articular cartilage interface, varying in thickness by several hundred micrometers across different species. Disruptions to this interface can cause severe damage to OC tissues, leading to osteoarthritis (OA), a debilitating and irreversible condition. Regenerative engineering approaches hold promise for addressing this issue by replicating the natural architecture and composition of native OC interface within a biomaterial scaffold. This study introduces a novel one-step bioprinting process using a twin-screw extruder that facilitates the fabrication of a unitary synthetic graft (USG), which mimics the native OC interfaces mineral concentration gradient. The newly developed USG is composed of an agarose-based cartilage layer and a bone layer, which consists of agarose enriched with 20% hydroxyapatite (w/vol). The USG features a gradient interface with the mineral concentration seamlessly transitioning from 0 to 20wt% from the cartilage to the bone layer. The mineral gradients in the USG and the native tissue were documented using thermogravimetric analysis (TGA), micro-CT, and energy dispersive x-ray (EDX). TGA revealed that the gradient transition length in the graft (647{+/-}21m) compared well to that of native OC tissue (633{+/-}124m) harvested from bovine knee. The strain sweep and frequency sweep tests in oscillatory shear evaluated the linear viscoelastic properties of the grafts, indicating a dominant storage modulus over loss modulus similar to that of native OC tissues. Additionally, the compressive and stress relaxation behaviors of the USGs were quantified using multi-extensional tests, highlighting the grafts ability to maintain structural integrity under mechanical stress. Furthermore, viability assays performed after bioprinting showed that chondrocytes and human fetal osteoblast cells successfully integrated and survived within their designated regions of the graft. The USGs engineered in this study exhibit properties that make them promising candidates for regenerating OC defects and restoring knee joint functionality.

bioengineering↗